Review Article
Open Access
Crystal structure analysis of dichloridobis(2 Isopropylimidazole)Zinc(II)
Prabu1*, K. Rajkumar2, AntoniSamy Clara2, K. Anbalagan2, A. SubbiahPandi1
1*Department of Physics, Presidency College (Autonomous), Chennai-600 005, India
2Department of Chemistry, Pondicherry University, Pondicherry 605 014, India
Prabu et al /Int.J. Chemical Concepts. 2019,5(1),pp 11-15.
Abstract
The
Crystal
structure
of
dichloridobis(2-Isopropylimidazole)Zinc(II)[Zn(2
Isopropylimdazole)2Cl2]. The structure of title compound, [C12H20Cl2N4Zn], Consists of
centrosymmetric monomeric units, in which the ZnII atom has a tetragonallydistorded coordination
involving two imidazole N atoms and two Cl atoms in the square plane [ Zn-N = 1.998(1)Å and Zn-Cl =
2.2541(7)Å. The angles Cl-Zn-Cl and N-Zn-N are 110.34(4)° and 116.07(12)°, respectively. In the
crystal there are no classical hydrogen bonds present.Crystal data were collected using CrysAlis CCD
Oxford DiffractionX-ray diffractometer. The structure was solved by direct methods and refined on F2 by
full-matrix least-squares procedures to the final R1 of 0.0370usingSHELXL programs.
Keywords
Imidazole, Zinc(II) and crystal structure.
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